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5 - S -Acetyl-5 -thiouridine (31) : PPh 3 (6.5 g, 24.6 mmol, 2.0 equiv.) was dissolved in dry THF (50 mL) and cooled to 0 C

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Silver nitrate (AgNO 3 ) in 1-dodecanethiol was sonicated to generate localized hot spots within the acoustic cavitation of collapsing bubbles during ultrasonic irradiation (reaction time: 10 min, power: 50%, temperature: ~ 160 )

NF-B is also directly regulated by H 2 O 2 -oxidation of cysteine residues in its DNA-binding region 136