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Where X is a sulfur and R 11 or R 11 is not hydrogen, the formula represents a thioester. Where X is a sulfur and R 11 is hydrogen, the formula represents a thiocarboxylic acid. Where X is a sulfur and R 11 is hydrogen, the formula represents a thioformate. On the other hand, where X is a bond, and R 11 is not hydrogen, the above formula represents a ketone group

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They add that as immunotherapies are being more commonly utilized as first- and second-line treatments, immunotoxicity and autoimmunity are emerging as the Achilles heel of immunotherapy. In their Cancer Immunology Research paper, Bluestone and colleagues briefly discuss immunotherapeutic strategies that can potentially prevent irAEs, such as targeting intratumoral T cells directly, using bispecific antibodies to enhance localized targeting of tumor, and using engineered cell therapies to fine-tune immune cell responses

The JAK/STAT signaling pathway: from bench to clinic