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The catalytic Cys groups in thiol have lower pKa values of 5.57.4, which in turn act as a H 2 O 2 -sensing center and react with H 2 O 2 under physiological conditions ( 2 O 2 level and forms an inter or intramolecular disulfide bond (SS), sulfenic acid (SOH), sulfinic acid (SO 2 H), and sulfonic acid (SO 3 H), which alters the structure, activity, and interactions of different proteins and enzymes and ultimately changes their localization and regulates the metabolism and physiology of plants

In the subsequent step, the Fenton reaction occurs, where Fe 2+ reacts with H 2 O 2 to produce OH, OH , and Fe 3+

Thurlbeck WM, Muller NL

Consistent with our results, recent literature also identifies elevated GDF15 levels in various chronic pain conditions beyond FM, including chronic low back pain and migraines

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