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This is most likely attributed to the inability of the constrained 13- and 14-membered macrocycles to adopt the proper transition states required for cleavage of the N-terminal peptide bond (Andersson et al., 2011) (Figure 8)

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Sharing knowledge, addressing concerns, and setting realistic expectations pave the way for successful, patient-centered care

In contrast, dietary B12 must be absorbed in the small intestine, which can be inefficient for those with digestive or absorption issues