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When energy is abundant, citrate is exported from mitochondria through the mitochondrial citrate carrier and cleaved by ATP citrate lyase to generate acetyl-CoA, which is then converted by acetyl-CoA carboxylase into malonyl-CoA, the first committed intermediate in fatty acid biosynthesis ( Once inside the cell, FFAs are bound by fatty acid-binding proteins (FABPs), which facilitate their distribution to distinct intracellular compartments and metabolic pathways ( These early steps in fatty acid handling have important consequences for macrophage function

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Abstraction of the hydrogen atom at C14 generates phytoprostanes G 1 (PPG 1 ) of type I, while hydrogen abstraction at C-11 yields PPG 1 of type II